火焰原子吸收光谱法测定苋菜中8种矿物元素

用空气-乙炔火焰原子吸收光谱法对苋菜中钾、钙、镁、铁、锌、铜、锰、铅8种矿物元素进行了测定,对样品前处理方法、酸度、共存元素干扰及元素线性范围进行了实验。在选定的实验条件下,可以用火焰原子吸收光谱法对苋菜中8种元素进行分别测定,互不干扰。方法的相对标准偏差为0.08%~3.17%(n=5),加标回收率为91.5%~102%。     

Continuous finite element schemes for a phase field model in two-layer fluid Bénard–Marangoni convection computations

In this article, we study a phase field model for a two-layer fluid where the temperature dependence of both the density (buoyancy forces) and the surface tension (Marangoni effects) is considered. The phase field model consisting of a modified Navier–Stokes equation, a Cahn–Hilliard phase field equation and an energy transport equation is derived through an energetic variational procedure. An appropriate variational form and a continuous finite element method are adopted to maintain the underlying energy law to its greatest extent. A few examples for Bénard–Marangoni convection in an Acetonitrile and n-Hexane two-layer fluid system heated from above will be computed to justify our phase field model and further show the good performance of our methods. In addition, an interesting experiment will be performed to show the competition between the Marangoni effects and the buoyancy forces.     

基于MIKE FLOOD的洪泽湖周边滞洪区洪水演进模拟研究

基于实测断面资料建立了研究区的一维水动力模型,基于高精度DEM以及1∶10000地形图建立了研究区的二维水动力模型,并用MIKE FLOOD将一维模型和二维模型进行耦合,构建了洪泽湖周边滞洪区一、二维耦合的洪水演进数学模型。利用2003年历史洪水资料对模型参数进行了率定,并以2007年历史洪水资料进行了验证。以洪泽湖百年一遇设计洪水为模型上边界,二河闸、三河闸以及高良涧闸的现行调度方案的水位-流量关系为模型下边界,对洪泽湖百年一遇设计洪水方案进行模拟计算,当蒋坝水位达到14.33m时,洪泽湖周边滞洪区开始滞洪,得到开始滞洪后不同时段研究区内各类洪水风险要素的动态分布情况以及最大淹没水深、淹没历时,验证了模型的合理性,可用于蓄滞洪区洪水演算分析。     

有机中微肥的生产及其应用前景

我国中低产田面积占总耕地面积70%以上,其中大部分存在有机质和中微量元素缺乏和肥料利用率低的问题。为防止中微量元素施入土壤后被固定而失效,提出利用废弃资源,生产有机中微肥(如氨基酸、木质素磺酸、腐植酸中微肥等),其生产成本比EDTA螯合中微肥低,并简要介绍了各种有机中微肥的生产工艺过程。只要做到测土施肥,有针对性加入有机中微肥,即可达到提高作物产量、品质,提高肥料利用率,提高土壤肥力的良好效果。     

ICP-MS法测定陶瓷容器中重金属元素的研究

采用电感耦合等离子体—质谱(ICP—MS)法同时测定了陶瓷容器中重金属元素PB、CA、Cr、Ni，对影响其测量的各种因素进行了较为详细的研究，确定了实验的最佳测定条件。结果表明，方法的检出限为0．002—0．008μg/L，回收率为90．0％-110．0％，RSD小于9．21％。该法准确、快速、简便，应用于陶瓷容器中重金属元素的测定，结果满意。     

FAST LINEAR ESTIMATION METHODS FOR VECTOR AUTOREGRESSIVE MOVING-AVERAGE MODELS

Abstract. Three linear methods for estimating parameter values of vector auto-regressive moving-average (VARMA) models which are in general at least an order of magnitude faster than maximum likelihood estimation are developed in this paper. Simulation results for different model structures with varying numbers of component series and observations suggest that the accuracy of these procedures is in most cases comparable with maximum likelihood estimation. Procedures for estimating parameter standard error are also discussed and used for identification of nonzero elements in the VARMA polynomial structures. These methods can also be used to establish the order of the VARMA structure. We note, however, that the primary purpose of these estimates is to generate initial estimates for the nonzero parameters in order to reduce subsequent computational time of more efficient estimation procedures such as exact maximum likelihood.     

ICP-AES法测定精制盐水中的微量元素

采用电感耦合等离子体发射光谱法测定二次精制盐水中Ca、Mg、Sr、Fe、Ba、S i等微量元素含量。方法简便、快速、精密度高,结果准确可靠。     

Effect of vermicomposting on the transformation of some trace elements in fly ash

One major constraint of the agricultural uses of fly ash (FA) is the low availability of different plant nutrients despite their high occurrence in the total amount. However, degrading FA through increased microbial activity can improve the availability of these nutrients substantially. It has been found that intestines of epigeic earthworms contain a high concentration of different microorganisms. Therefore, in the present study we addressed the effects of vermicomposting technology on the solubility of some micronutrient cations (Fe, Mn, Cu, and Zn) and some heavy metals (Pb, Cd, and Cr) in different combinations of fly ash and organic matter, applied in the form of cow dung (CD). Various combinations of FA and CD were treated with and without an epigeic earthworm (Eisenia fetida) and the solubility of different trace elements in the treatments were estimated periodically. The results revealed that the inclusion of epigeic earthworm Eisenia fetida in different combinations of fly ash and cow dung converted a considerable amount of the micronutrients into bio-available forms. On the other hand, the solubility of heavy metals tended to be reduced by the microorganisms, presumably by formation of some organo-metallic complex. Application of these vermicomposted FA and CD combinations to a red lateritic soil was found to improve the soluble Fe, Mn, Cu, and Zn status of the soil. Furthermore, the use of vermicomposted FA and CD (1:1) in potato cultivation demonstrated that use of this mixture at 10 ton per hectare (t ha⁻¹; fresh weight) was able to compensate 80% of the recommended NPK fertiliser, along with farm yard manure application, without compromising the crop yield.     

MIKE21模型在南新联圩洪水模拟中的应用

为了分析江西省南新联圩防洪保护区在圩提溃决后洪水在区内的演进过程,根据南新联圩防洪保护区周围湖泊、河流及圩区情况,建立了模拟保护区内洪水演进的MIKE21模型。分别采用2010年和2012年实测洪水资料对模型进行率定和验证,结果表明模型具有较高的模拟精度。在赣江50 a一遇洪水叠加湖口22.5 m洪水位(1954年型)的工况下,利用所建立的模型对防洪保护区内的淹没水深、流速和洪水演进过程等进行计算分析,获得了南新联圩防洪保护区发生溃堤后的受灾发展情况。研究成果可为南新联圩防洪预警及时发布、转移财产、逃生避险等提供技术支撑。     

Geochemical implications of trace elements and sulfur in the saturate, aromatic and resin fractions of crude oil from the Mara and Mara Oeste fields, Venezuela

Ten trace elements (Cr, Zn, Fe, Mn, Cu, Co, Ni, Mo, V and Sr) and sulfur were determined in the saturate, aromatic and resin fractions of 15 crude oils from Mara (DM) and Mara Oeste (DMO) fields of the Maracaibo Basin, Venezuela. The oils studied are classified as unaltered or altered by biodegradation. In the altered oil, the depletion of n-alkanes, the absence of isoprenoids and the presence of steranes and hopanes unaltered by biodegradation are indicative of moderate biodegradation. The elements Zn, Fe, Mn, Cu, Ni, and Sr were detected in the saturated hydrocarbon fraction; Cr and V were detected in the aromatic fraction in addition to the above elements; whereas the elements detected for the resin fraction were Cr, Zn, Fe, Cu, Ni, Mo, V, and Sr. Co was not detected in any fractions of the oils analyzed. Sulfur was found in all fractions of the oils studied. It was proposed that Fe, Zn, Sr, and Mn could have entered the oil during migration or Fe, Zn and Mn as pollutants during oil extraction. Cr and Cu may be of biological origin and Mo could be incorporated into the reservoir through bacteria. Only S, V, and Ni in the resin fractions can be used as indicators of the origin and correlation of Mara and Mara Oeste oils. Based on the results obtained in this work, it can be established that the V/(V+Ni) ratio in the resin fraction can be used as a correlation parameter, for these oils.